Hour Test I (pink) Name__________________________ CHM 1045 (Dr. Light) Soc.Sec.Num._____________________ February 9, 1996 8:00 am Recitation Section_______ This exam consists of 4 pages. Make sure you have one of each. Print your name at the top of each page now. A blank scratch sheet and a periodic chart are provided. Please do not write on the periodic chart, and turn it in with your test. You may discard the scratch sheet. Show your work on calculations, including unit conversions, and give answers in the correct units and appropriate number of significant figures. In problems involving molecular and formula weights, you may use values rounded to the nearest 0.1 amu. If anything confuses you or is not clear, raise your hand and ask! (6) 1. Mercury has a density of 13.6 g/cm3. A laboratory beaker weighs 10.2 g empty and 31.7 g when filled with water. What would be the weight of the beaker if filled with mercury (i.e. the total weight of beaker plus mercury). (Remember, the density of water is 1.00 g/cm3. (4) 3. Name the following compounds: Be(OH)2 ____________________ Li3PO4 ____________________ (4) 4. Write the formulas for the following: iron (II) bromite ____________________ dinitrogen pentoxide ____________________ (8) 5. Give the atomic symbol, including Z, A, and q for atoms or ions containing the following numbers of particle: (a) 15 p, 16 n, 15 e (b) 28 p, 30 n, 26 e (6) 6. Give the number of protons, neutrons, and electrons in the following: Nuclide protons neutrons electrons 65Zn+2 _______ ________ ________ 112Cd ________ ________ ________ (3) 7. Which of the following men (circle your answer) working with the cathode ray tube discovered and characterized the charge/mass ratio of the cathode ray particles? Becquerel, Rutherford, Thompson, Millikan, Dalton, Priestly (7) 8. Balance the following chemical equations: (a) ____La2O3 + ____H2O -----> ____La(OH)3 (b) ____Al + ____HCl -----> ____AlCl3 + ____H2 (15) 9. Complete and balance the chemical equations for: (a) Reaction of potassium with water. (b) Complete combustion of butyric acid (C4H8O2). (c) Reaction of sulfuric acid with sodium hydroxide. (6) 10. Calculate the number of grams in 93.8 moles of P2O5. (8) 11. Calculate the number of molecules in 33.1 g of ethyl alcohol, C2H6O. (10) 12. A compound containing only carbon, hydrogen and oxygen was shown by combustion analysis to consist of 31.6% C and 5.31% H. What is its empirical formula? 13. Given the following chemical equation: 2 HI + Ba(OH)2 -----> BaI2 + 2 H2O (8) (a) 3.25 g of HI are dissolved in water and the solution is titrated with a solution of Ba(OH)2. The titration requires 45.3 mL of the Ba(OH)2 solution. What is the molarity of the Ba(OH)2 solution? (6) (b) 22 mL of a solution of 0.15 M Ba(OH)2 is mixed with 38 mL of a solution of 0.15 M HI. Which is the limiting reagent? (Show your work). (6) (c) In part (b) above, how many grams of BaI2 will be formed? (3) (d) In part (b) above, how many moles (or millimoles) of the excess reagent will be left?