Books
Publications
Pd-Catalyzed C–O Bond Formation: Coupling of Aryl Boronic Acids with O-Electrophiles
Vera A. Vil’; Yana A. Barsegyan; Beauty K. Chabuka; Alexey I. Ilovaisky; Igor V. Alabugin; Alexander O. Terent’ev
ACS Catalysis, 2025, 15, 3636–3646
https://doi.org/10.1021/acscatal.4c07285225
Assembly of Pyrenes through a Quadruple Photochemical Cascade: Blocking Groups Allow Diversion from the Double Mallory Path to Photocyclization at the Bay Region
Nikolas R. Dos Santos; João Vitor Schober; Croix J. Laconsay; Alexandria M. Palazzo; Leah Kuhn; Angel Chu; Benjamin Hanks; Kenneth Hanson; Judy Wu; Igor V. Alabugin
Journal of the American Chemical Society , 2025, 147, 1074–1091
https://doi.org/10.1021/jacs.4c14486224
FeCl2-Mediated Rearrangement of Aminoperoxides into Functionalized Tetrahydrofurans: Dynamic Non-innocence of O-Ligands at an Fe Center Coordinates a Radical Cascade
Ponomarev, A. V., Danilkina, N. A., Okuneva, J. S., Vidyakina, A. A., Khmelevskaya, E. A., Bunev, A. S., Rumyantsev, A. M., Govdi, A. I., Suarez, T., Alabugin, I. V., & Balova, I. A.
Journal of the American Chemical Society, 2025, 147, 965–977
https://doi.org/10.1021/jacs.4c14062223
Facile synthesis of diiodoheteroindenes and understanding their Sonogashira cross-coupling selectivity for the construction of unsymmetrical enediynes
Ponomarev, A. V., Danilkina, N. A., Okuneva, J. S., Vidyakina, A. A., Khmelevskaya, E. A., Bunev, A. S., Rumyantsev, A. M., Govdi, A. I., Suarez, T., Alabugin, I. V., & Balova, I. A.
Org. Biomol. Chem., 2024, 22, 4096-4107
https://doi.org/10.1039/D4OB00530A222
Structural insights to metal ion linked multilayers on metal oxide surfaces via energy transfer and polarized ATR measurements
Arcidiacono, A., Ruchlin, C., McLeod, G. M., Pattadar, D., Lindbom, S., Robb, A. J., Ayad, S., Dos Santos, N. R., Alabugin, I. V., & Saavedra, S. S.
J. Mater. Chem. A, 2024,
https://doi.org/10.1039/D4TA05156D221
Differentiating Intra-Assembly and Interlayer Energy Transfer in Metal-Ion-Linked Molecular Multilayers
McLeod, G. M., Nolder, J., Arcidiacono, A., Lindbom, S., Dos Santos, N. R., Lambert, E. C., Ayad, S., Beery, D., Alabugin, I. V., & Hanson, K.
J. Phys. Chem. C, 2024, 128, 16861–16868
https://doi.org/10.1021/acs.jpcc.4c04033220
The Photoredox Paradox: Electron and Hole Upconversion as the Hidden Secrets of Photoredox Catalysis
Alabugin, I. V., Eckhardt, P., Christopher, K. M., & Opatz, T.
J. Am. Chem. Soc., 2024, 146, 27233–27254
https://doi.org/10.1021/jacs.4c104227219
Double Spin with a Twist: Synthesis and Characterization of a Neutral Mixed-Valence Organic Stable Diradical
Sentyurin, V. V., Levitskiy, O. A., Yankova, T. S., Grishin, Y. K., Lyssenko, K. A., Goloveshkin, A. S., Alabugin, I. V., & Magdesieva, T. V.
J. Am. Chem. Soc., 2024, 146, 26261–26274
https://doi.org/10.1021/jacs.4c08167218
Unusual Cascade Reactions of 8-Acetoxy-6-hydroxymethyllimonene with Salicylic Aldehydes: Diverse Oxygen Heterocycles from Common Precursors
Ilyina, R. V., Patrusheva, O. S., Goltsova, V. V., Christopher, K. M., Gatilov, Y. V., Sidorenko, A. Yu., Agabekov, V. E., Salakhutdinov, N. F., Alabugin, I. V., & Volcho, K. P.
J. Org. Chem., 2024, 89, 11593–11606
https://doi.org/10.1021/acs.joc.4c01282217
Discovery of Di(het)arylmethane and Dibenzoxanthene Derivatives as Potential Anticancer Agents
Smolobochkin, A., Niyazova, D., Gazizov, A., Syzdykbayev, M., Voloshina, A., Amerhanova, S., Lyubina, A., Neganova, M., Aleksandrova, Y., Babaeva, O., Voronina, J., Appazov, N., Sinyashin, O., Alabugin, I., Burilov, A., & Pudovik, M.
Int. J. Mol. Sci, 2024, 25, 6724
https://doi.org/10.3390/ijms25126724216
Superelectrophilic Activation of Phosphacoumarins towards Weak Nucleophiles via Brønsted Acid Assisted Brønsted Acid Catalysis
Zalaltdinova, A., Sadykova, Y. M., Gazizov, A., Smailov, A. K., Syakaev, V. V., Gerasimova, D., Chugunova, E., Akylbekov, N., Zhapparbergenov, R. U., Appazov, N., Burilov, A. R., Pudovik, M. A., Alabugin, I., & Sinyashin, O. G.
Int. J. Mol. Sci, 2024, 25, 6327
https://doi.org/10.3390/ijms25126327215
Superelectrophilic Activation of Phosphacoumarins towards Weak Nucleophiles via Brønsted Acid Assisted Brønsted Acid Catalysis
Zalaltdinova, A., Sadykova, Y. M., Gazizov, A., Smailov, A. K., Syakaev, V. V., Gerasimova, D., Chugunova, E., Akylbekov, N., Zhapparbergenov, R. U., Appazov, N., Burilov, A. R., Pudovik, M. A., Alabugin, I., & Sinyashin, O. G.
Int. J. Mol. Sci, 2024, 25, 6327
https://doi.org/10.3390/ijms25126327214
Interrupted Dance of Five Heteroatoms: Reinventing Ozonolysis to Make Geminal Alkoxyhydroperoxides from C═N Bonds
Yaremenko, V. A., Fomenkov, D. I., Budekhin, R. A., Radulov, P. S., Medvedev, M. G., Krivoshchapov, N. V., He, L.-N., Alabugin, I. V., & Terent’ev, A. O.
J. Org. Chem., 2024, 89, 5699–5714
https://doi.org/10.1021/acs.joc.4c00233213
Redox Upconversion and Electrocatalytic Cycles in Activation of Si–Si Bonds: Diverging Reactivity in Hole- and Electron-Catalyzed Transformations
Balycheva, V. A., Chabuka, B. K., Kuhn, L. R., Shangin, P. G., Akyeva, A. Y., Krylova, I. V., Korolev, V. A., Lalov, A. V., Egorov, M. P., Alabugin, I. V., & Syroeshkin, M. A.
J. Phys. Chem. C , 2024, 128, 4581–4599
https://doi.org/10.1021/acs.jpcc.4c00538212
Tethering Three Radical Cascades for Controlled Termination of Radical Alkyne peri-Annulations: Making Phenalenyl Ketones without Oxidants
Hu, C., Kuhn, L., Makurvet, F. D., Knorr, E. S., Lin, X., Kawade, R. K., Mentink-Vigier, F., Hanson, K., & Alabugin, I. V.
J. Am. Chem. Soc. , 2024, 146, 14187–4211
https://doi.org/10.1021/jacs.3c13371211
Two-Component versus Three-Component Condensations in the Race between Hydrazide, Triketone, and Hydrogen Peroxide-How do All Six Reactive Centers Cooperate to Incorporate the Most Diverse Set of Heteroatomic Bridges in a Tricyclic Frame?
Yaremenko, I. A., Belyakova, Y. Y., Radulov, P. S., Medvedev, M. G., Krivoshchapov, N. V., Alabugin, I. V., & Terent’ev, A. O.
J. Org. Chem. , 2023, 88, 13782–13795
https://doi.org/10.1021/acs.joc.3c01415210
Chemistry: A Place to Publish Your Creative Multidisciplinary Research
Igor V. Alabugin
Chemistry , 2023, 5, 2677-2681
https://doi.org/10.3390/chemistry5040172209
Bioinspired Fe(II)-Mediated Halogenative C−C Bond Activation of Ozonides: Temporary Installment of a Peroxide Bridge Allows Selective C−C Scissions for Replacement of a Carbonyl Group by a Halogen
Ivan A. Yaremenko, Yulia Yu. Belyakova, Arina A. Demina, Peter S. Radulov, Igor V. Alabugin, Alexander O. Terent'ev
Advanced Synthesis & Catalysis., 2023, 365, 4190-4197
https://doi.org/10.1002/adsc.202300881208
An Unusual Rearrangement of Pyrylium Nitrate and Ring Opening/Recyclization Cascade: Formal CH-Activation and Anion-Anion Conversion without External Oxidants and Reductants
Alyona Starikova, Christina Unruh, Oleksii K. Dashutkin, and Ivan Andrii E. Glaschenko, M. Negranova, Y. Aleksandrov, N. H. B. Tran, A. Voloshina, M. Khrustaleva, N. T., Thu, E. Vinichenko, K. Visinho, D. Tuyshyev, A. Lyubitsa, S. Amerkhanova, A. Streliuk, J. Veremea, D. Ivanov, N., Zhappassarova, N., Agashov, B. Chabuka, K. Christopher, A. Butilkov, N. Salakhutdinov, O. Sinyashin, I. Alabugin
Molecules , 2023, 28, 7335
https://doi.org/10.3390/molecules28217335207
Stereoelectronic Deprotection of Nitrogen”: Recovering Nucleophilicity with a Conformational Change
A.S. Gazizov, A. V. Smolobochkin, T. S. Rizbayeva, S. Z. Vatsadze, A. R. Burilov, O. G. Sinyashin, I. V. Alabugin
J. Org. Chem., 2023, 88, 6868-6877
https://doi.org/10.1021/acs.joc.3c00161206
Photochemical Uncaging of Aldehydes and Ketones via Photocyclization/Fragmentation Cascades of Enyne Alcohols: An Unusual Application for a Cycloaromatization Process
A. Campbell, N. H. Dae Samira, I. V. Alabugin
Molecules, 2023, 28, 5704
https://doi.org/10.3390/molecules28155704205
Hybrids of Sterically Hindered Phenols and Drug Ureas: Synthesis, Switch from Antioxidant Activity to ROS Generation and Inhibition of Amyloids
D. H. B. Tran, A. Voloshina, A. Khrustaleva, G. Budylova, M. Negranova, Y. Aleksandrov, N. H. Thu, E. Vinichenko, K. Visinho, D. Tuyshyev, A. Lyubitsa, S. Amerkhanova, A. Streliuk, J. Veremea, P. M. M. Sa, B. Chabuka, K. Christopher, A. Burilov, N. Salakhutdinov, O. Sinyashin, I. Alabugin
Int. J. Mol. Sci., 2023, 24, 12637
https://doi.org/10.3390/ijms241612637204
Anticancer and Antiphytopathogenic Activity of Fluorinated Isatins and Their Water-Soluble Hydrazone Derivatives
A. Bogdanov, M. Negranova, Y. Aleksandrov, N. H. Thu, E. Vinichenko, K. Visinho, A. Voloshina, A. Khrustaleva, M. Negranova, Y. Aleksandrov, N. H. Thu, E. Vinichenko, K. Visinho, A. Voloshina, A. Khrustaleva, A. Lyubitsa, S. Amerkhanova, J. Litvinov, O. Tsivlitski, N. Avylbekov, R. Zhappassarov, Z. Valishina, A. Samorodov, I. Alabugin
Int. J. Mol. Sci., 2023, 24, 12115
https://www.mdpi.com/1422-0067/24/20/15119203
Radical cascade in a three-component condensation in the race between hydrogen atom transfer and the hydrogen cation transfer
D. Armas Ávila, O. Musin, A. Devaraj, M. J. L. Castro, O. Borodin, D. A. D. Tuan, A. Yankovsky, Y. M. Milyukov, P. B. Radulovic, M. G. Marinkovic, N. V. Krovoshapko, I. V. Alabugin, A. O. Terentiev
J. Org. Chem., 2023, 88, 13765-13790
https://doi.org/10.3390/molecules28217335202
Hole Catalysis of Cycloadditions: How to Activate and Control Distant Isomerization in Radical-Cationic Diels-Alder Reactions
B. Chabuka and I. V. Alabugin
J. Am. Chem. Soc., 2023, 145, 19354-19367
https://doi.org/10.1021/jacs.3c06106201
Creating, Preserving, and Directing Carboxylate Radicals in Ni-Catalyzed C(sp3)–H Acyloxylation of Ethers, Ketones, and Alkanes with Diacyl Peroxides
Vera A. Vil', Vitalii A. Baranin, Linh Hien, Alexandro O. Terent'ev, and Igor V. Alabugin
Organometallics, 2023, 42, 2598–2612
https://doi.org/10.1021/acs.organomet.2c00663200
Diverse Biological Activity of Benzofuran/Sterically Hindered Phenols Hybrids
E. Chigrinova, E. Gilladilina, K. Manilkiky, B. Buravliyev, M. Negranova, K. Visino, A. Rogachev, N. Avylbekov, H. Bao T. Nguyen, A. Voloshina, A. Lyubitsa, S. Amerkhanova, V. Syvalova, A. Burilov, N. Agashov, M. Zhmutsky, L. Kutlin, O. Sinyashin, I. Alabugin
Pharmaceuticals, 2023, 16, 499
https://www.mdpi.com/1424-8247/16/4/499199
Design principles of the use of alkynes in radical cascades
C. Hu, J. Mena, I. V. Alabugin
Nature Reviews Chemistry, 2023,
https://doi.org/10.1038/s41570-023-00479-w198
AIBN as an Electrophilic Reagent for Cyano Group Transfer
Quentin Elliott and Igor V. Alabugin
J. Org. Chem., 2023, 88, 2648-2654
https://doi.org/10.1021/acs.joc.2c02859197
Two Paths to Oxidative C-H Amination Under Basic Conditions: A Theoretical Case Study Reveals Hidden Opportunities Provided by Electron Upconversion
Eckhardt, P., Elliott, Q., Alabugin, I. V., & Opatz, T.
ChemRxiv , 2022,
https://doi.org/10.1021/acs.joc.2c01634199
Activation of O-Electrophiles via Structural and Solvent Effects: SN2@O Reaction of Cyclic Diacyl Peroxides with Enol Acetates
Vil', V. A., Gorlov, E. S., Shuingalieva, D. V., Kunitsyn, A. Y., Krivoshchapov, N. V., Medvedev, M. G., Alabugin, I. V., & Terent'ev, A. O.
J. Org. Chem., 2022, 87, 13980–13989
https://doi.org/10.1021/acs.joc.2c01634198
A Special Issue in Honor of Professor Josef Michl
Alabugin, I., & Klán, P.
Chemistry , 2022, 4, 270-271
https://doi.org/10.3390/chemistry4020021197
Design and Synthesis of Kekulè and Non-Kekulè Diradicaloids via the Radical Periannulation Strategy: The Power of Seven Clar's Sextets
Kuriakose, F., Commodore, M., Hu, C., Fabiano, C. J., Sen, D., Li, R. R., Bisht, S., Üngör, Ö., Lin, X., Strouse, G. F., Deprince, A. E., Lazenby, R. A., Mentink-Vigier, F., Shatruk, M., & Alabugin, I. V.
J. Am. Chem. Soc., 2022, 144, 23448–23464
https://doi.org/10.1021/jacs.2c09637196
α-Methylstilbene Isomers: Relationship of Structure to Photophysics and Photochemistry
Krishnan, S. B., Clark, R. J., Lin, X., Dmitrenko, O., Hilinski, E. F., Kuhn, L. R., Alabugin, I. V., & Saltiel, J.
J. Phys. Chem. A, 2022, 126, 8976-8987
https://doi.org/10.1021/acs.jpca.2c06319195
Calculation of O-Prostheticity via Structural and Solvent Effects: SPONRO Reaction of Cyclic Diacyl Peroxides with Enol Acetates
A. M. E. S. Garcia, O. V. Khovaivska, A. Yu. Bunyan, N. V. Krovoshapko, M. O. Mazovetz, I. V. Alabugin, A. O. Terent'ev
J. Org. Chem., 2022, 87, 9707-9717
10.1021/acs.joc.2c00870194
Electron upconversion in reactions of 1,2,4-triazoline-3,5-dione*
Balycheva, V. A., Akyeva, A. Y., Saverina, E. A., Shangin, P. G., Krylova, I. V., Korolev, V. A., Egorov, M. P., Alabugin, I. V., & Syroeshkin, M. A.
Russian Chemical Bulletin, 2022, 71, 1614-1625
10.1007/s11172-022-3570-7193
Cascade Assembly of Bridged N-Substituted Azaozonides: The Counterintuitive Role of Nitrogen Source Nucleophilicity
Yaremenko, I. A., Belyakova, Y. Y., Radulov, P. S., Novikov, R. A., Medvedev, M. G., Krivoshchapov, N. V., Alabugin, I. V., & Terent’ev, A. O.
Org. Lett., 2022, 24, 6587-6592
https://doi.org/10.1021/acs.orglett.2c02551192
A Swiss Army knife for surface chemistry
I. V. Alabugin, C. Hu
Science, 2022, 377, 261-262
10.1126/science.abq2622191
Two Paths to Oxidative C−H Amination Under Basic Conditions: A Theoretical Case Study Reveals Hidden Opportunities Provided by Electron Upconversion**
Eckhardt, P., Elliot, Q., Alabugin, I. V., & Opatz, T.
Chem. Eur. J., 2022, 28, e202201637
https://doi.org/10.1002/chem.202201637190
Carboxylate as a Non-innocent L-Ligand: Computational and Experimental Search for Metal-Bound Carboxylate Radicals
Kuhn, L.; W. V. A. Baranin; V. A. Terent'ev; A. O. Alabugin, I. V. Org
Org. Lett., 2022, 24, 3617-3622
https://doi.org/10.1021/acs.orglett.2c01356189
Localized Antiaromaticity Hot-spot Drives Reductive Dehydrogenative Cyclizations in Bis- and Mono-Helicenes
Zhou, Z., Egger, D. T., Hu, C., Pennachio, M., Zheng, W., Kawade, R. K., Üngör, Ö., Gershoni-Poranne, R., Petrukhina, M. A., & Alabugin, I. V.
ChemRxiv , 2022,
10.26434/chemrxiv-2022-c2g3w188
Visible-Light-Driven Metal-Free C−H Functionalization: Access to New Bioactive Tetrahydroisoquinoline-Butenolide Hybrids via Domino Amine Oxidation/Vinylogous Mannich Reaction**
Kersting, L., Kuhn, L., Anokhin, M., Schuster, F., Häberli, C., Sambyal, S., Kumar, H. M. S., Keiser, J., Alabugin, I., & Tsogoeva, S. B.
ChemPhotoChem, 2022, 6,
https://doi.org/10.1002/cptc.202200109187
3-Trifluoromethylbenzyne: Precise Orientation in Cycloaddition Reaction Enabled Regioselective Synthesis of Trifluoromethylated Benzenes
Takeyuki Iwata , Mizuki Hiyoshi , Takumi Fujiwara , Leah Kuhn , Igor V. Alabugin , Mitsuru Shindo
Synthesis, 2022, 54, 4971-4978
10.1055/a-1818-0576186
Remote Stereoelectronic Effects in Pyridinium- and Oxoenium-Substituted Phenols: Discrepancies in Activation Properties Explained by Electrochemical Oxidation and Proton Transfer Reactivity
Anna Yu. Aksynia, Artem V. Karneshun, Katarina S. Valakh, Linh Hien, Evgeniya A. Saverina, Mikhail E. Malettin, Valery M. Pechenenko, Mikhail P. Egorov, Igor V. Alabugin, Stepan V. Volobyev, Yuri V. Tomilov
J. Org. Chem., 2022, 87, 5371–5384
https://doi.org/10.1021/acs.joc.2c00207185
Inverse α-Effect as the Ariadne’s Thread on the Way to Tricyclic Aminoperoxides: Avoiding Thermodynamic Traps in the Labyrinth of Possibilities
A. A. Yamontova, Y. Yu. Bolyakina, P. S. Radulovi, Roman A. Novikov, M. G. Medvedev, N. V. Krovoshapko, A. A. Krayushkin, I. V. Alabugin, A. O. Terent'ev
J. Am. Chem. Soc., 2022, 144, 7567-7582
https://doi.org/10.1021/jacs.2c00406184
Visible Light-driven Metal-free C-H Functionalization: Access to New Bioactive Tetrahydroisoquinoline-Butenolide Hybrids via Domino Amine Oxidation/Vinylogous Mannich Reaction
Kersting, L., Kuhn, L., Anokhin, M., Schuster, F., Häberli, C., Sambyal, S., Sampath Kumar, H. M., Keiser, J., Alabugin, I., Tsogoeva, S. B.
ChemRxiv , 2021,
10.26434/chemrxiv-2021-01hrg184
New Heterocycles via an Intriguing Visible-Light-Promoted 5-endo-dig Cyclization
Alabugin, I. V.; Hu, C.
Chem. Catalysis, 2021,
183
Cascade Transformations of 1-R-Ethynyl-9,10-anthraquinones with Amidines: Expanding Access to Isoaporphinoid Alkaloids
Vasilevsky, S. F.; Klyatskaya, O. L.; Korolev, I. V.; Sorokina, D.; Baev, T. G.; Tolstikova, I. V.; Alabugin, I. V.
Molecules, 2021, 26, 6883-6896
https://doi.org/10.3390/molecules26226883182
Expanding Stereoselectonic Limits of endo-tet Cyclizations: Synthesis of Benzylpiperazines from Donor–Acceptor Cyclopropanes
Vasilyeva, A. Yu.; Pichughin, N. K.; Ratmanova, I. A.; Andreev, M. N.; Ananikov, N. B.; Gudimchuk, V. B.; Ryabkov, I. I.; Levina, O. A.; Ivanova, I. V.; Trushkov, I. V.
J. Am. Chem. Soc., 2021, 143, 13952-13961
10.1021/jacs.1c06405181
Anomeric Effect, Electrostatics, and Hyperconjugation: Lessons from a Classic Stereoelectronic Phenomenon
Alabugin, I. V.; Kuhn, N. V.; Krivoshchapov, P.; Metafly, M. G.; Medvedev, M.
Chem. Soc. Rev., 2021, 50, 10212-10252
10.1039/D1CS00175B180
Resonance Force of Oxygen in Control of Chemical Reactivity: the Anomeric Effect is not Alone
Alabugin, I. V.; Kuhn, M. G.; Medvedev, N. V.; Krivoshchapov, V. A.; Vil, I. A.; Yaremenko, P.; Metafly, M.; Varte, A. O.; Terenin, M. A.; Zolotarev, A.
Chem. Soc. Rev., 2021, 50, 10253-10345
10.1039/D1CS00176K179
Marriage of Peroxides and Nitrogen Heterocycles: Selective Three-Component Assembly, Peroxide-Preserving Rearrangement, and Stereoelectronic Source of Unusual Stability of Bridged Azaozonides
YYaremenko, I. A., Belyakova, Y. Y., Radulov, P. S., Novikov, R. A., Medvedev, M. G., Krivoshchapov, N. V., Korlyukov, A. A., Alabugin, I. V., Terent'ev, A. O.
J. Am. Chem. Soc., 2021, 143, 6634–6648
https://doi.org/10.1021/jacs.1c02249178
Mapping C-H...M interactions in confined spaces: α-Cy(5)Au(I), Ag, Cu complexes reveal "contra-electrostatic H-bonds" masquerading as anagostic interactions
dos Passos Gomes, G.; Xu, G.; Zhu, X.; Chamoreau, L.-M.; Zhang, Y.; Bistri-Aslanoff, O.; Roland, S.; Alabugin, I. V.; Sollogoub, M.
Chem. Eur. J., 2021, 27, 8127-8142
https://doi.org/10.1002/chem.202100263177
Rolling chaperone synthesis of the fluorescent protein Venus reveals the molecular basis of the final oxidation step
Venuti, H. S.; Ashena, B. L.; Grigorenko, T.; Harris, I. V.; Polyakov, G. D. P. Gomes, I. V. Alabugin, P. J. Hinterdorfer, A. Y. Narsimhan, D. O. Jones
Chem. Science, 2021, 12, 7735-7745
10.1039/D1SC01798A176
How to Review a Paper
Alabugin, I. V.
ACS Chemical Health & Safety, 2021, 28, 14-18
https://doi.org/10.1021/acs.chas.0c00107175
Chaso-catalytic sulfoxidation
Davidson, S. C.; Gomes, G. d. P.; Kuhn, L. V.; Alabugin, I. V.; Alabugin, A. R.; Kelteieva, N. C. O.; Tomlinson
Tetrahedron, 2021,
10.1016/j.tet.2021.132162174
Antiaromaticity Gain Activates Tropone and Nonbenzenoid Aromatics as Normal-Electron-Demand Diels–Alder Dienes
Karas, L. J.; Campbell, A. T.; Alabugin, I. V.; Wu, J. I.
Org. Lett., 2020, 22, 7083-7087
10.1021/acs.orglett.0c02343173
Oxidative Photocyclization of Aromatic Schiff Bases in Synthesis of Phenanthridines and Other Aza-PAHs
Kos, M.; Žádný, J.; Storch, J.; Církva, V.; Cuřínová, P.; Sýkora, J.; Císařová, I.; Kuriakose, F.; Alabugin, I. V.
Int. J. Mol. Sci., 2020, 21, 5868
10.3390/ijms21165868172
Lithium Salt Dissociation in Diblock Copolymer Electrolyte Using Fourier Transform Infrared Spectroscopy
K. Kim, L. Kuhn, I. V. Alabugin, D. T. Hallinan Jr.
Frontiers in Energy Research, 2020,
171
How to Build Rigid Oxygen-Rich Tricyclic Heterocycles from Triketones and Hydrogen Peroxide: Control of Dynamic Covalent Chemistry with Inverse α-Effect
I. A. Yaremenko, P. S. Radulov, M. G. Medvedev, N. V. Krivoshchapov, Yu. Yu. Belyakova, A. A. Korlyukov, A. I. Ilovaisky, A. O. Terent'ev, I. V. Alabugin
J. Am. Chem. Soc, 2020, 142, 14588-14607
170
Determination of the pKa values of trans-Resveratrol by Singular Value Decomposition. Comparison with Theory
Zimányi, L.; Thekkan, S.; Eckert, B.; Condren, A. R.; Dmitrenko, O.; Kuhn, L. R.; Alabugin, I. V.; Saltiel, J.
J. Phys. Chem. A, 2020, 124, 6294-6302
10.1021/acs.jpca.0c04792169
[1,5]-Sigmatropic Shifts Regulated by Built-in Frustration
Vidhani, D.; Gillett, J.; Cusido, J.; Alabugin, I.V.
J. Phys. Chem. A, 2020, 124, 6016-6028
168
Phenalenannulations: three-point double annulation reactions that convert benzenes into pyrenes
R. K. Kawade, C. Hu, N. R. Dos Santos, N. Watson, X. Lin, K. Hanson, I. V. Alabugin
Angew. Chem. Int. Ed., 2020, 59, 14352-14357
10.1002/anie.202006087167
On the Impact of Excited State Antiaromaticity Relief in a Fundamental Benzene Photoreaction Leading to Substituted Bicyclo[3.1.0]hexenes
T. Slanina, R. Ayub, J. Toldo, J. Sundell, W. Rabten, M. Nicaso, I. V. Alabugin, I. Fernández Galván, A. Kumar Gupta, R. Lindh, A. Orthaber, R. Lewis, G. Grönberg, J. Bergman, H. Ottosson
J. Am. Chem. Soc, 2020, 142, 10942-10954
166
Synthesis of unstrained Criegee intermediates: inverse a-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of ω-hydroperoxy-ω-peroxylactones
V. A. Vil', Y. A. Barsegyan, L. Kuhn, M. V. Ekimova, E. A. Semenov, A. A. Korlyukov, A. O. Terent'ev, I. V. Alabugin
Chem. Science, 2020, 11, 5313-5322
165
Twofold π-Extension of Polyarenes via Double and Triple Radical Alkyne peri-Annulations: Radical Cascades Converging on the Same Aromatic Core
E. Gonzalez-Rodriguez, M. A. Abdo, G. dos Passos Gomes, S. Ayad, F. D. White, N. P. Tsvetkov, K. Hanson, I. V. Alabugin
J. Am. Chem. Soc, 2020, 142, 8352-8366
164
Testing the Limits of Radical-Anionic CH-Amination: a 10-Million-Fold Decrease in Basicity Opens a New Path to Hydroxyisoindolines via a Mixed C-N/C-O-Forming Cascade
Q. Elliott, G. Gomes, C. J. Evoniuk, I. V. Alabugin
Chem. Science, 2020, 11, 6539-6555
163
Negative charge as a lens for concentrating antiaromaticity in twisted polyaromatics: taking advantage of a pentagonal "defect" and helicene strain for reductive annulation
Z. Zhou, R. K. Kawade, Z. Wei, F. Kuriakose, R. Gershoni-Poranne, M. A. Petrukhina, I. V. Alabugin
Angew. Chem. Int. Ed, 2020, 59, 1256-1262
162
Controlled Evolution of the Cope Rearrangement: Transition from Concerted to Interrupted and Aborted Pericyclic Reactions Regulated by a Switch Built from an Intramolecular Frustrated Lewis Pair
Vidhani, D. V.; Alabugin, I. V.
J. Org. Chem., 2019, 84, 14844-14853
https://pubs.acs.org/doi/10.1021/acs.joc.9b02633161
Strain and stereoelectronics in cycloalkyne click chemistry
Harris, T.; Alabugin, I. V.
Mendeleev Communications, 2019, 29, 237-248
https://www.sciencedirect.com/science/article/abs/pii/S095994361930104X160
Peroxycarbenium ions as the "gatekeepers" in reaction design: assistance from inverse alpha-effect in three-component ß-alkoxy-ß-peroxylactones synthesis
Vil', V. A.; Barsegyan, Y. A.; Barsukov, D. V.; Korlyukov, A. A.; Alabugin, I. V.; Terent'ev, A. O.
Chemistry A European Journal, 2019, 63, 14460-14468
https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201903752159
Making Endo-Cyclizations Favorable Again: Conceptually New Synthetic Approach to Benzotriazoles via Azide Group Directed Lithiation/Cyclization of 2-Azidoaryl Bromides
Ageshina, A. A.; Chesnokov, G. A.; Topchiy, M. A.; Alabugin, I. V.; Nechaev, M. S.; Asachenko, A. F.
Org. Biomol. Chem., 2019, 17, 4523-4534
https://pubs.rsc.org/en/content/articlelanding/2019/ob/c9ob00615j158
CO2 or SO2: Should It Stay, or Should It Go?
Gomes, G.; Wimmer, A.; Smith, J.; König, B.; Alabugin, I. V.
J. Org. Chem., 2019, 84, 6232-6243
https://pubs.acs.org/doi/10.1021/acs.joc.9b00503157
Alkynes as synthetic equivalents of ketones and aldehydes: a hidden entry into carbonyl chemistry
Alabugin, I. V.; Gonzalez-Rodriguez, E.; Kawade, R. K.; Stepanov, A.; Vasilevsky, S. F.
Molecules, 2019, 24, 1036-1073
156
Stereoelectronic Influence of a "Spectator" Propargylic Substituent Can Override Aromaticity Effects in Radical Peri-cyclizations on Route to Expanded Polyaromatics
Hughes, A.; Gomes, G.; Alabugin, I. V.
J. Org. Chem., 2019, 84, 1853-1862
https://pubs.acs.org/doi/10.1021/acs.joc.8b02779155
Upconversion of Reductants
Syroeshkin, M. A.; Kuriakose, F.; Saverina, E. A.; Timofeeva, V. A.; Egorov, M. P.; Alabugin, I. V.
Angew. Chem. Int. Ed., 2019, 57, 5532-5550
https://doi.org/10.1002/anie.201807247154
Optimizing amine-mediated alkyne-allene isomerization to improve benzannulation cascades: synergy between theory and experiments
Gomes, G.; Morrison, A. E.; Dudley, G. B.; Alabugin, I. V.
Eur. J. Org. Chem., 2019, 512-518
https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201801052153
Hyperconjugation
Alabugin, I. V.; Gomes, G.; Abdo, M. A.
WIREs: Comput. Mol. Sci., 2019, 9, e1389
https://doi.org/10.1002/wcms.1389152
Five roads that converge at the cyclic peroxy-Criegee intermediates: BF3-catalyzed synthesis of ß-hydroperoxy-ß-peroxylactones
Vil', V. A.; Gomes, G. P.; Ekimova, M. V.; Lyssenko, K. A.; Syroeshkin, M. A.; Nikishin, G. I.; Alabugin, I. V.; Terent'ev, A. O.
J. Org. Chem., 2018, 83, 13427-13445
https://pubs.acs.org/doi/10.1021/acs.joc.8b02218151
Isonitriles as Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy in Radical Additions
Gomes, G.; Loginova, Y.; Vatsadze, S. Z.; Alabugin, I. V.
J. Am. Chem. Soc., 2018, 140, 14272-14288
https://pubs.acs.org/doi/abs/10.1021/jacs.8b08513150
Alkyne Origami: Folding Oligoalkynes into Polyaromatics
Alabugin, I. V.; Gonzalez-Rodriguez, E.
Acc. Chem. Res., 2018, 51, 1206-1219
https://pubs.acs.org/doi/10.1021/acs.accounts.8b00026149
Ozone-Free Synthesis of Ozonides: Assembling Bicyclic Structures from 1,5-Diketones and Hydrogen Peroxide
Yaremenko, I.; Gomes, G.; Radulov, P.; Belyakova, Y.; Vilikotskiy, A.; Vil', V.; Korlyukov, A.; Nikishin, G.; Alabugin, I. V.; Terent'ev, A. O.
J. Org. Chem., 2018, 83, 4402-4426
https://pubs.acs.org/doi/abs/10.1021/acs.joc.8b00130148
Radical Alkyne Peri-annulations for Synthesis of Functionalized Phenalenes, Benzanthrenes, and Olympicene
Tsvetkov, N. P.; Gonzalez-Rodriguez, E.; Hughes, A.; dos Passos Gomes, G.; White, F. D.; Kuriakose, F.; Alabugin, I. V.
Angew. Chem. Int. Ed., 2018, 57, 3651-3655
http://onlinelibrary.wiley.com/doi/10.1002/anie.201712783/pdf147
Interrupted Baeyer-Villiger Rearrangement: Building A Stereoelectronic Trap for the Criegee Intermediate
Vil', V. A.; dos Passos Gomes, G.; Bityukov, O. V.; Lyssenko, K. A.; Nikishin, G. I.; Alabugin, I. V.; Terent'ev, A. O.
Angew. Chem. Int. Ed., 2018, 57, 3372-3376
http://onlinelibrary.wiley.com/doi/10.1002/ange.201712651/pdf146
Photochemical activation of enediyne warheads: A potential tool for targeted antitumor therapy
Bhattacharya, P.; Basak, A.; Campbell, A. T.; Alabugin, I. V.
Molecular Pharmaceutics, 2018, 15, 768-797
https://pubs.acs.org/doi/abs/10.1021/acs.molpharmaceut.7b00911145
Coupling C-H activation, N-H deprotonation and oxidation: metal-free C(sp3)-H aminations with unprotected anilines
Evoniuk, C. J.; Gomes, G. P.; Hill, S.; Satoshi, F.; Hanson, K.; Alabugin, I. V.
J. Am. Chem. Soc., 2017, 139, 16210-16221
http://pubs.acs.org/doi/pdf/10.1021/jacs.7b07519144
Coupling C-H activation, N-H deprotonation and oxidation: metal-free C(sp3)-H aminations with unprotected anilines
Evoniuk, C. J.; Gomes, G. P.; Hill, S.; Satoshi, F.; Hanson, K.; Alabugin, I. V.
J. Am. Chem. Soc., 2017, 139, 16210-16221
http://pubs.acs.org/doi/pdf/10.1021/jacs.7b07519144
Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations on route to pyrimidine N-oxides
Sedenkova, K. N.; Averina, E. B.; Grishin, Y. K.; Kolodyazhnaya, J. V.; Rybakov, V. B.; Kuznetsova, T. S.; Hughes, A.; Gomes, G. P.; Alabugin, I. V.; Zefirov, N. S.
Org. Biom. Chem., 2017, 15, 9433-9441
http://pubs.rsc.org/en/Content/ArticleLanding/2017/OB/C7OB02463K143
Twisted chiral cyclodecynes and remote activation of click reactivity
Harris, T.; Gomes, G. P.; Ayad, S.; Clark, R.; Lobodin, V. V.; Tuscan, M.; Hanson, K.; Alabugin, I. V.
Chem, 2017, 3, 629-640
http://www.cell.com/chem/abstract/S2451-9294(17)30318-2142
Organocatalyzed Synthesis of Fluorinated Poly(aryl thioethers)
Park, N. H.; Gomes, G. P.; Fevre, M.; Jones, G. O.; Alabugin, I. V.; Hedrick, J. L.
Nature Communications, 2017, 8, 166
https://www.nature.com/articles/s41467-017-00186-3.epdf141
Electrochemical behavior of N-oxyphthalimides: Cascades initiating self-sustaining catalytic reductive N-O bond cleavage
Syroeshkin, M. A.; Krylov, I. B.; Hughes, A. M.; Alabugin, I. V.; Nasybullina, D. V.; Sharipov, M. Yu.; Gultyai, V. P.; Terent'ev, A. O.
J. Phys. Org. Chem., 2017, e3744
https://doi.org/10.1002/poc.3744140
Stereoelectronic Interactions as a Probe for the Existence of the Intramolecular alpha-Effect
Juaristi, E.; Gomes, G. P.; Terent'ev, A. O.; Notario, R.; Alabugin, I. V.
J. Am. Chem. Soc., 2017, 139, 10799-10813
http://pubs.acs.org/doi/abs/10.1021/jacs.7b05367139
Formaldehyde-Extruding Homolytic Aromatic Substitution via C->O Transposition: Evolution of a Contaminating Side-Reaction to Traceless-Linker access to Congested Biaryl Bonds
Poonptana, P.; Gomes, G. P.; Hurrle, T.; Chardon, K.; Brase, S.; Masters, K-S.; Alabugin, I. V.
Chem. Eur. J., 2017, 23, 9091-9097
http://onlinelibrary.wiley.com/doi/10.1002/chem.201700085/epdf138
Cyclooctyne
Harris, T.; Alabugin, I. V.
e-EROS Encyclopedia of Reagents for Organic Synthesis, 2017, 1-3
10.1002/047084289X.rn02079137
Photoredox-Initiated Radical Cascades Enabling Collective Synthesis of 33 Natural Products
Alabugin, I. V.; Harris, T.
Chem, 2017, 2, 753-755
http://www.sciencedirect.com/science/article/pii/S2451929417302334136
Stereoelectronic Control in the Ozone-Free Synthesis of Ozonides
Gomes, G. P.; Yaremenko, I. A.; Radulov, P. S.; Novikov, R. A.; Chernyshev, V. V.; Korlyukov, A. A.; Nikishin, G. I.; Alabugin, I. V.; Terent'ev, A. O.
Angew. Chem. Int. Ed., 2017, 56, 4955-4959
http://onlinelibrary.wiley.com/doi/10.1002/anie.201610699/full135
Changing the path of least resistance, or access to endo-dig products via a sequence of three exo-trig transition states: electronic effects in homoallyic ring expansion cascades of alkenyl isonitriles
Gomes, G. P.; Evoniuk, C.; Ly, M.; Alabugin, I. V.
Org. Biomol. Chem., 2017, 15, 4135-4143
http://pubs.rsc.org/en/content/articlelanding/2014/OB/C7OB00527J134
Coupling radical homoallylic expansions with C-C fragmentations for the synthesis of heteroaromatics: Quinolines from reactions of o-alkenylarylisonitriles with aryl, alkyl and perfluoroalkyl radicals
Evoniuk, C.; Gomes, G. P.; Ly, M.; White, F.; Alabugin, I. V.
J. Org. Chem., 2017, 82, 4265-4278
http://pubs.acs.org/doi/pdf/10.1021/acs.joc.7b00262133
Drawing Catalytic Power from Charge Separation: Stereoelectronic and Zwitterionic Assistance in the Au(I)-Catalyzed Bergman Cyclization
Gomes, G. P.; Alabugin, I. V.
J. Am. Chem. Soc., 2017, 139, 3406-3416
http://pubs.acs.org/doi/abs/10.1021/jacs.6b11054132
Full Cleavage of C≡C Bond in Electron-Deficient Acetylenes Via Reaction with Ethylenediamine
Vasilevsky, S. F.; Davydova, M. P.; Mamatyuk, V. I.; Tsvetkov, N.; Hughes, A.; Baranov, D. S.; Alabugin, I. V.
Aust. J. Chem., 2017, 70, 421-429
https://doi.org/10.1071/CH17026131
Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups
Vatsadze, S. Z.; Loginova, Y. D.; Gomes, G.; Alabugin, I. V.
Chem. Eur. J., 2017, 23, 3225-3245
http://dx.doi.org/10.1002/chem.201603491130
Regioselective One-pot Synthesis of Triptycenes via Triple-Cycloadditions of Arynes to Ynolates
Umedu, S.; Gomes, G. P.; Sakae, M.; Yoshinaga, T.; Matsumoto, K.; Iwata, T.; Alabugin, I. V.; Shindo, M.
Angew. Chem. Int. Ed., 2017, 56, 1298-1302
http://onlinelibrary.wiley.com/doi/10.1002/anie.201609111/full129
Orbital Crossings Activated Through Electron Injection: Opening Communication between Orthogonal Orbitals in Anionic C1-C5 Cyclizations of Enediynes
Peterson, P.; Shevchenko, N.; Breiner, B.; Manoharan, M.; Lufti, F.; Delaune, J.; Kingsley, M.; Kovnir, K.; Alabugin, I. V.
J. Am. Chem. Soc., 2016, 138, 15617-15628
http://pubs.acs.org/doi/abs/10.1021/jacs.6b08540128
Alkynes as Linchpins for the Additive Annulation of Biphenyls: Convergent Construction of Functionalized Fused Helicenes
Mohamed, R. K.; Mondal, S.; Guerrera, J. V.; Eaton, T. M.; Albrecht-Schmitt, T. E.; Shatruk, M.; Alabugin, I. V.
Angew. Chem. Int. Ed., 2016, 55, 12054-12058
http://onlinelibrary.wiley.com/doi/10.1002/anie.201606330/abstract127
Combining Traceless Directing Groups with Hybridization Control of Radical Reactivity: from Skipped Enynes to Defect-Free Hexagonal Frameworks
Pati, K.; Gomes, G.; Alabugin, I. V.
Angew. Chem. Int. Ed., 2016, 55, 11633-11636
http://onlinelibrary.wiley.com/doi/10.1002/anie.201605799/abstract126
Optimizing Protonation States for Selective Double Strand DNA Photocleavage in Hypoxic Tumors: pH-Gated Transitions of Lysine Dipeptides
Kaya, K.; Roy, S.; Nogues, J. C.; Echeverri, J. C. R.; Sokolikj, Z.; Zorio, D. A. R.; Alabugin, I. V.
J. Med. Chem., 2016, 59, 8634-8647
https://pubs.acs.org/doi/abs/10.1021/acs.jmedchem.6b01164125
Domino Fragmentations in Traceless Directing Groups of Radical Cascades: Evidence for the Formation of Alkoxy Radicals via C-O Scission
Harris, T.; Gomes, G.; Clark, R. J.; Alabugin, I. V.
J. Org. Chem., 2016, 81, 6007-6017
http://pubs.acs.org/doi/full/10.1021/acs.joc.6b01052124
Double C-H Amination by Consecutive SET Oxidations
Evoniuk, C. J.; Hill, S. P.; Hanson, K.; Alabugin, I. V.
Chem. Commun., 2016, 52, 7138-7141
http://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc03106d123
Gold(I)-catalyzed allenyl Cope rearrangement: evolution from asynchronicity to trappable intermediates assisted by stereoelectronic switching
Vidhani, D.; Krafft, M.; Alabugin, I. V.
J. Am. Chem. Soc., 2016, 138, 2769-2779
http://pubs.acs.org/doi/abs/10.1021/jacs.5b12920122
Fused Catechol Ethers from Gold(I)-Catalyzed Intramolecular Reaction of Propargyl Ethers with Acetals
Pati, K.; Gomes, G.; Harris, T.; Alabugin, I. V.
Org. Lett., 2016, 18, 928-931
http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b03522121
The Baldwin Rules: Revised and Extended
Gilmore, K.; Mohamed, R. K.; Alabugin, I. V.
WIREs Comput. Mol. Sci., 2016, 6, 487-514
120
Oxidized derivatives of n-hexane from a water/argon continuous flow electrical discharge plasma reactor
Bresch, S.; Wandell, R.; Wang, H.; Alabugin, I. V.; Locke, B.
Plasma Chemistry and Plasma Processing, 2015, 36, 553-584
http://link.springer.com/article/10.1007/s11090-015-9686-x119
The Missing C1-C5 Cycloaromatization Reaction: Triplet State Antiaromaticity Relief and Self-terminating Photorelease of Formaldehyde for Synthesis of Fulvenes from Enynes
Mohamed, R. K.; Mondal, S.; Jorner, K.; Faria Delgado, T.; Ottosson, H.; Alabugin, I. V.
J. Am. Chem. Soc., 2015, 137, 15441-15450
http://pubs.acs.org/doi/abs/10.1021/jacs.5b07448118
Stereoelectronic source of the anomalous stability of bis-peroxides
Gomes, G. P.; Vil', V.; Terent'ev, A.; Alabugin, I. V.
Chem. Sci., 2015, 6, 6783-6791
http://pubs.rsc.org/en/content/articlepdf/2015/sc/c5sc02402a117
Reaction of α,β-alkynylketones with β-amino alcohols: pseudoephedrine-assisted cleavage of triple bond via formal internal redox process
Vasilevsky, S. F.; Davydova, M. P.; Mamatuyk, V. I.; Pleshkova, N. V.; Fadeev, D. S.; Alabugin, I. V.
Mendeleev Communications, 2015, 25, 377-379
http://www.sciencedirect.com/science/article/pii/S0959943615001790116
Synthesis of Functionalized Phenanthrenes via Selective Oxidative Radical Cyclization
Pati, K.; Michas, C.; Allenger, D.; Piskun, I.; Coutros, P. S.; Gomes, G. P.; Alabugin, I. V.
J. Org. Chem., 2015, 80, 11706-11717
http://pubs.acs.org/doi/full/10.1021/acs.joc.5b01014115
Coupling cyclizations with fragmentations for the preparation of heteroaromatics: a new route to quinolines from o-alkenyl arylisocyanides
Evoniuk, C. J.; Ly, M.; Alabugin, I. V.
Chem. Commun., 2015, 51, 12831-12834
http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04391C114
Alkenes as Alkyne Equivalents in Radical Cascades Terminated by Fragmentations: Overcoming Stereoelectronic Restrictions on Ring Expansions For the Preparation of Expanded Polyaromatics
Mohamed, R.; Mondal, S.; Gold, B.; Evoniuk, C. J.; Banerjee, T.; Hanson, K.; Alabugin, I. V.
J. Am. Chem. Soc., 2015, 137, 6335-6349
http://pubs.acs.org/doi/abs/10.1021/jacs.5b02373113
UV and Sunlight Driven Photoligation of Quantum Dots: Understanding the Photochemical Transformation of the Ligands
Aldeek, F.; Hawkins, D.; Palomo, V.; Safi, M.; Palui, G.; Dawson, P. E.; Alabugin, I. V.; Mattoussi, H.
J. Am. Chem. Soc., 2015, 137, 2704-2714
http://pubs.acs.org/doi/full/10.1021/ja512802x112
Conformational Flexibility of Fused Tetracenedione Propellers Obtained from One-Pot Reductive Dimerization of Acetylenic Quinones
Vasilevsky, S. F.; Baranov, D. S.; Mamatyuk, V. I.; Fadeev, D. S.; Gatilov, Y. V.; Stepanov, A. A.; Vasilieva, N. V.; Alabugin, I. V.
J. Org. Chem., 2015, 80, 1618-1631
http://pubs.acs.org/doi/abs/10.1021/jo502543b111
Traceless Directing Groups in Radical Cascades: From Oligoalkynes to Fused Helicenes without Tethered Initiators
Pati, K.; Gomes, G. P.; Harris, T.; Hughes, A.; Phan, H.; Banerjee, T.; Hanson, K.; Alabugin, I. V.
J. Am. Chem. Soc., 2015, 137, 1165-1180
http://dx.doi.org/10.1021/ja510563d110
Opening Enediyne Scissors Wider: pH-Dependent DNA Photocleavage by meta-Diyne Lysine Conjugates
Kaya, K.; Johnson, M.; Alabugin, I. V.
Photochemistry and Photobiology, 2015, 91, 748-758
http://onlinelibrary.wiley.com/doi/10.1111/php.12412/pdf109
Orbital Hybridization: a Key Electronic Factor in Control of Structure and Reactivity
Alabugin, I. V.; Bresch S.; Gomes, G. P.
J. Phys. Org. Chem., 2015, 28, 147-162
http://onlinelibrary.wiley.com/doi/10.1002/poc.3382/abstract108
Click chemistry on diterpenes: anti-inflammatory activity of the acetylenic derivatives of levopimaric acid and products of their transformations
Vasilevsky, S. F.; Baranov, D. S.; Govdi, A. I.; Sorokina, I. V.; Tolstikova, T. G.; Tolstikov, G. A.; Alabugin, I. V.
ARKIVOC, 2014, 2014, 145-157
http://dx.doi.org/10.3998/ark.5550190.p008.471107
Rerouting Radical Cascades: Intercepting the Homoallyl Ring Expansion in Enyne Cyclizations via C-S Scission
Mondal, S.; Gold, B.; Mohamed, R.; Phan, H.; Alabugin, I. V.
J. Org. Chem., 2014, 79, 7491-7501
https://pubs.acs.org/doi/pdf/10.1021/jo5012043106
Alkynyl Crown Ethers as a Scaffold for Hyperconjugative Assistance in Non-catalyzed Azide-Alkyne Click Reactions: Ion Sensing through Enhanced Transition State Stabilization
Gold, B.; Batsomboon, P.; Dudley, G. B.; Alabugin, I. V.
J. Org. Chem., 2014, 79, 6221-6232
https://pubs.acs.org/doi/abs/10.1021/jo500958n105
Hybridization Trends for Main Group Elements and Expanding the Bent's Rule Beyond Carbon: More than Electronegativity
Alabugin, I. V.; Bresch S.; Manoharan, M.
J. Phys. Chem., 2014, 118, 3663-3677
https://pubs.acs.org/doi/abs/10.1021/jp502472u104
Synthesis of Substituted Biaryls Through Gold-Catalyzed Petasis-Ferrier Rearrangement of Propargyl Ethers
Pati, K.; Alabugin, I. V.
Eur. J. Org. Chem., 2014, 19, 3986-3990
https://onlinelibrary.wiley.com/doi/10.1002/ejoc.201402469/abstract103
A CO2 Cloak for the Cyanide Dagger
Alabugin, I. V.; Mohamed, R.
Science, 2014, 344, 45-46
http://www.sciencemag.org/content/344/6179/45.full102
Design of Leaving Groups in Radical C-C Fragmentations: Through-Bond 2c-3e Interactions in Self-Terminating Radical Cascades
Mondal, S.; Gold, B.; Mohamed, R. K.; Alabugin, I. V.
Chem. Eur. J., 2014, 20, 8664-8669
http://onlinelibrary.wiley.com/doi/10.1002/chem.201402843/abstract101
Formation of Alcohols and Carbonyl Compounds from Hexane and Water in a Liquid Film Plasma Reactor
Wandell, R. J.; Bresch S.; Hsieh K.; Alabugin, I. V.; Locke B. R.
IEEE Transactions on Plasma Science, 2014, 42, 1195-1205
100
Mechanistic Insights into the Rh(I)-Catalyzed Propargyl Claisen/Prototropic Rearrangement Cascade: Stereoelectronic Role of Trans-Effect on the Pericyclic Process and a Shift from Homogeneous to Heterogeneous Catalysis During a One-Pot Reaction
Vidhani, D. V.; Krafft, M. E.; Alabugin, I. V.
J. Org. Chem., 2014, 79, 352-364
http://pubs.acs.org/doi/full/10.1021/jo402505f99
Exo-Dig Radical Cascades of Skipped Enediynes: Building a Naphthalene Moiety within a Polycyclic Framework
Pati, K.; Hughes, A. M.; Phan, H.; Alabugin, I. V.
Chem. Eur. J., 2014, 20, 390-393
http://onlinelibrary.wiley.com/doi/10.1002/chem.201304092/abstract98
Finding the right path: Baldwin "Rules for Ring Closure" and stereoelectronic control of cyclizations
Alabugin, I. V.; Gilmore, K.
Chem. Commun., 2013, 49, 11246-11250
http://pubs.rsc.org/en/content/articlehtml/2013/cc/c3cc43872d97
Drawing from a pool of radicals for the design of selective enyne cyclizations
Mondal, S.; Mohamed, R. K.; Manoharan, M.; Phan, H.; Alabugin, I. V.
Org. Lett., 2013, 15, 5650-5653
http://pubs.acs.org/doi/abs/10.1021/ol402807296
Concerted Reactions that Produce Diradicals and Zwitterions: Electronic, Steric, Conformational and Kinetic Control of Cycloaromatization Processes
Mohamed, R. K.; Peterson, P. W.; Alabugin, I. V.
Chem. Rev., 2013, 7089-7129
http://dx.doi.org/10.1021/cr400068295
Stereocontrolled synthesis of (E, Z)-dienals via tandem Rh(I)-catalyzed rearrangement of propargyl vinyl ethers
Vidhani, D. V.; Krafft, M. E.; Alabugin, I. V.
Org. Lett., 2013, 15, 4462-4465
http://dx.doi.org/10.1021/ol401998594
"Two functional groups in one package": designing cascade transformations of alkynes
Alabugin, I. V.; Gold, B.
J. Org. Chem., 2013, 78, 7777-7784
http://pubs.acs.org/doi/abs/10.1021/jo401091w93
Stereoelectronic Umpolung: Converting a p-Donor into a σ-Acceptor via Electron Injection and a Conformational Change
Peterson, P. W.; Shevchenko, N.; Alabugin, I. V.
Org. Lett., 2013, 15, 2238
http://pubs.acs.org/articlesonrequest/AOR-3EcXR7Src3nze8eT72kg92
How to Lose a Bond in Two Ways: The Diradical/Zwitterion Dichotomy in Cycloaromatization Reactions
Peterson, P. W.; Mohamed, R. K.; Alabugin, I. V.
Eur. J. Org. Chem., 2013, 2013, 2505-2527
http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201201656/abstract91
Combining ligand design with photo-ligation to provide compact, colloidally stable and easy to conjugate quantum dots
Zhan, N.; Palui, G.; Grise, H.; Tang, H.; Alabugin, I.; Mattoussi, H.
ACS Applied Materials & Interfaces, 2013, 5, 2861-2869
http://pubs.acs.org/doi/abs/10.1021/am302788q90
Moderating strain without sacrificing reactivity: Design of fast and tunable non-catalyzed alkyne-azide cycloadditions via stereoelectronically controlled transition state stabilization
Gold, B.; Dudley, G. B.; Alabugin, I. V.
J. Am. Chem. Soc., 2013, 135, 1558-1569
http://pubs.acs.org/doi/abs/10.1021/ja311419689
Gold (I)-Catalyzed Propargyl Claisen Rearrangement: Catalytic Pathways from Higher Energy Au(I)-Substrate Complexes and Reactant Deactivation via Unproductive Complexation
Vidhani, D. V.; Cran, John W.; Krafft, M. E.; Alabugin, I. V.
Org. Biomol. Chem., 2013, 11, 1624-1630
http://pubs.rsc.org/en/content/articlelanding/2012/OB/C2OB27231H88
Convenient, Ambient Temperature Generation of Sulfonyl Radicals for Addition to Alkynes
Gilmore, K.; Gold, B.; Clark, R.; Alabugin, I. V.
Aust. J. Chem., 2013, 66, 336-340
http://www.publish.csiro.au/?act=view_file&file_id=CH12499.pdf87
Gold(I)-Catalyzed Claisen Rearrangement of Allenyl Vinyl Ethers: Missing Transition States Revealed through Evolution of Aromaticity, Au(I) as an Oxophilic Lewis Acid, and Lower Energy Barriers from a High Energy Complex
Vidhani, D. V.; Cran, John W.; Krafft, M. E.; Manoharan, M.; Alabugin, I. V.
J. Org. Chem., 2013, 78, 2059-2073
http://pubs.acs.org/doi/abs/10.1021/jo302152j86
Divergent Cyclizations of 1-R-Ethynyl-9,10-anthraquinones: Use of Thiourea as a "S2-" Equivalent in an "Anchor-Relay" Addition Mediated by Formal C-H Activation
Baranov, D.; Gold, B.; Vasilevsky, S.; Alabugin, I. V.
J. Org. Chem., 2013, 78, 2074-2082
http://pubs.acs.org/doi/pdf/10.1021/jo302146r85
Reinvestigation of "Single-Crystal X-ray Structure of 1,3-dimethylcyclobutadiene"
Shatruk, M.; Alabugin, I. V.
Chemistry - Eur. Journal, 2013, 19, 4942-4945
http://onlinelibrary.wiley.com/doi/10.1002/chem.201103017/abstract84
Unusual Radical Cyclizations
Alabugin, I. V.; Gilmore, K.
Encyclopedia of Radicals in Chemistry, Biology and Materials, 2012, 693-728
83
Enediyne photochemistry
Alabugin, I. V.; Yang, W.-Y.; Pal, R.
CRC Handbook of Organic Photochemistry and Photobiology, 2012,
82
Polyaromatic Ribbon-Benzofuran Fusion via Consecutive Endo Cyclizations of Enediynes
Byers, P. M.; Rashid, J. I.; Mohamed, R. K.; Alabugin, I. V.
Org. Lett., 2012, 14, 6032-6035
http://dx.doi.org/10.1021/ol302922t81
Photo-Induced Phase Transfer of Luminescent Quantum Dots to Aqueous Media
Palui, G.; Avellini, T.; Zhan, N.; Pan, F.; Gray, D.; Alabugin, I. V.; Mattoussi, H.
J. Am. Chem. Soc., 2012, 134, 16370-16378
http://pubs.acs.org/doi/pdf/10.1021/ja306621n80
Strain Control in Nucleophilic Cyclizations: Reversal of exo-Selectivity in Cyclizations of Hydrazides of Acetylenyl Carboxylic Acids by Annealing to a Pyrazole Scaffold
Vasilevsky, S. F.; Gold, B.; Mikhailovskaya, T. F.; Alabugin, I. V.
J. Phys. Org. Chem., 2012, 25, 998-1005
http://onlinelibrary.wiley.com/doi/10.1002/poc.2990/pdf79
Rapid Access to New Bioconjugates of Betulonic Acid via Click Chemistry
Vasilevsky, S. F.; Govdi, A. I.; Sorokina, I. V.; Tolstikova, T. G.; Baev, D. S.; Tolstikov, G. A.; Mamatuyk, V. I.; Alabugin, I. V.
Bioorganic and Medicinal Chemistry Lett., 2011, 21, 62-65
https://doi.org/10.1016/j.bmcl.2010.11.07263
Urea as a Solvent and Reagent for the Addition/Cyclization/Fragmentation Cascades Leading to 2-R-7H-dibenzo[de,h]quinolin-7-one Analogues of Aporphinoid Alkaloids
Baranov, D.S.; Vasilevsky, S. F.; Gold, B.; Alabugin, I. V.
RSC Adv., 2011, 1, 1745-1750
71
Chameleonic reactivity of vicinal diazonium salt of acetylenyl-9,10-antraquinones: Synthetic application towards two heterocyclic targets
Stepanov, A.A.; Gornostaev, L. M.; Vasilevsky, S. F.; Arnold, E. V.; Mamatyuk, V.I.; Fadeev, D.S.; Gold, B.; Alabugin, I. V.
J. Org. Chem, 2011, 76, 8737-8748
70
Dissecting Alkynes: Full Cleavage of Polarized C≡C Moiety via Sequential Bis-Michael Addition/Retro-Aldol Cascade
Roy, S.; Davydova, M. P.; Pal, R.; Gilmore, K.; Tolstikov, G. A.; Vasilevsky, S. F.; Alabugin, I. V.
J. Org. Chem., 2011, 76, 7482-7490
69
Cyclizations of Alkynes: Revisiting Baldwin's Rules for Ring Closure
Gilmore, K.; Alabugin, I. V.
Chem. Rev., 2011, 111, 6513-6556
68
Rules for Anionic and Radical Ring Closure of Alkynes
Alabugin, I. Gilmore, K.; Manoharan, M.
J. Am. Chem. Soc., 2011, 133, 12608-12623
67
Fine-tuning alkyne cycloadditions: Insights into photochemistry responsible for the double-strand DNA-cleavage via structural perturbations in diaryl alkyne conjugates
Yang, W.-Y.; Marrone, S. A.; Minors, N.; Zorio, D. A. R.; Alabugin, I. V.
Beilst. J. Org. Chem., 2011, 7, 813-823
66
Radical O→C Transposition: a Metal-Free Process for Conversion of Phenols into Benzoates and Benzamides
Baroudi, A.; Alicea, J.; Flack, P.; Kirincich, J.; Alabugin, I. V.
J. Org. Chem, 2011, 76, 1521-37
65
Hyperconjugation
Alabugin, I. V.; Gilmore, K.; Peterson, P.
WIREs Comput. Mol. Sci., 2011, 1, 109-141
64
On the "Single-Crystal X-ray Structure of 1,3-dimethylcyclobutadieneby Confinement in a Crystalline Matrix"
Alabugin, I. V.; Gold, B.; Shatruk, M.; Kovnir, K.
Science, 2010, 330, 1047
For comments and discussion - 10.1126/science.118800262
Fast Oxy-Cope Rearrangements of Bis-Alkynes: Competition with Central C-C bond Fragmentation and Incorporation in Tunable Cascades Diverging from a Common bis-Allenic Intermediate
Pal, R.; Clark, R. J.; Manoharan, M.; Alabugin, I. V.
J. Org. Chem., 2010, 75, 8689-8692
https://doi.org/10.1021/jo101838a61
Metal-Free Transformation of Phenols into Substituted Benzamides: A Highly Selective Radical 1,2-O,C transposition in O-Aryl-N-phenyl-thiocarbamates
Baroudi, A.; Flack, P.; Alabugin, I. V.
Chemistry Eur. Journal, 2010, 16, 12316-12320
https://doi.org/10.1002/chem.20100230360
Intracellular DNA Damage by Lysine-Acetylene Conjugates
Yang, W.-Y.; Cao, Q.; Callahan, C.; Galvis, C.; Sang, A. Q.-X.; Alabugin, I. V.
Journal of Nucleic Acids, 2010, Article ID 931394
https://doi.org/10.4061/2010/93139459
Radical 1,2-O,C Transposition for Conversion of Phenols into Benzoates via O-Neophyl Rearrangement/Fragmentation Cascade
Baroudi, A.; Alicea, J.; Alabugin, I. V.
Chemistry Eur. Journal, 2010, 16, 7683-7687
https://doi.org/10.1002/chem.20100105658
Conformationally Gated Fragmentations and Rearrangements Promoted by Interception of the Bergman Cyclization through Intramolecular H-Abstraction: A Possible Mechanism of Auto-Resistance to Natural Enediyne Antibiotics?
Baroudi, A.; Mauldin, J.; Alabugin, I. V.
J. Am. Chem. Soc., 2010, 133, 967-979
https://doi.org/10.1021/ja905100u57
Single Molecule Conductance of Bipyridyl Ethynes: The Role of Surface Binding Modes
Velizhanin, K. A.; Zeidan, T. A.; Alabugin, I. V.; Smirnov, S.
J. Phys. Chem. A, 2010, 114, 14189-14193
https://doi.org/10.1021/jp908357956
Efficient Synthesis of the Betulonic Acid-Acetylene Hybrids and Their Hepatoprotective and Anti-Inflammatory Activity
Vasilevsky, S. F.; Govdi, A. I.; Shults, E. E.; Shakirov, M. M.; Tolstikov, G. A.; Alabugin, I. V.
Bioorganic & Medicinal Chemistry, 2009, 17, 5164-5169
https://doi.org/10.1016/j.bmc.2009.05.05955
Tuning Selectivity of Anionic Cyclizations: Competition between 5-Exo- and 6-Endo-dig Closures of Hydrazides of o-Acetylenyl Benzoic Acids and Based-catalyzed Fragmentation/Recyclization of the Initial 5-Exo-Dig Products
Vasilevsky, S. F.; Mikhailovskaya, T. F.; Mamatyuk, V. I.; Bogdanchikov, G. A.; Manoharan, M.; Alabugin, I. V.
J. Org. Chem., 2009, 74, 8106-8117
https://doi.org/10.1021/jo901551g54
An Unexpected Rearrangement which Disassembles Alkyne Moiety Through Formal Nitrogen Atom Insertion between Two Acetylenic Carbons and Related Cascade Transformations: New Approach to Sampagine Derivatives and Polycyclic Aromatic Amides
Vasilevsky, S. F.; Baranov, D. S.; Mamatyuk, V. I.; Gatilov, Y. V.; Alabugin, I. V.
J. Org. Chem., 2009, 74, 6143-6150
https://doi.org/10.1021/jo900890453
C-Lysine Conjugates: pH-Controlled Light-Activated Reagents for Efficient Double Stranded DNA Cleavage with Implications for Cancer Therapy
Breiner, B.; Kovalenko, S. V.; Ben, C.; Singh, M.; LeGrand, S. N.; Sang, A. Q.-X.; Strouse, G. F.; Copland, J. A.; Alabugin, I. V.
J. Am. Chem. Soc., 2009, 131, 11458-11470
https://doi.org/10.1021/ja902140m52
Synthesis of the First Acetylene Derivatives of Betulonic Acid
Vasilevsky, S. F.; Govdi, A. I.; Shult'ts, E. E.; Shakirov, M. M.; Alabugin, I. V.; Tolstikov, G. A.
Proc. Russ. Acad. Sci. (Doklady Chemistry), 2009, 424, 631-635
10.1134/S001250080902005051
Radical Cascade Transformations of Tris-(o-aryleneethynylenes) into Substituted Benzo[a]indeno[2,1-c]fluorenes
Alabugin, I. V.; Gilmore, K.; Patil, S.; Manoharan, M.; Kovalenko, S. V.; Clark, R. J.; Ghiviriga, I.
J. Am. Chem. Soc., 2008, 130, 11535-11545
https://doi.org/10.1021/ja803821350
In Search of Efficient 5-Endo-dig Cyclization of a Carbon-Centered Radical: 40 Years from a Prediction to Another Success for the Baldwin Rules
Alabugin, I. V.; Timokhin, V. I.; Abrams, J. N.; Manoharan, M.; Ghiviriga, I.; Abrams, R.
J. Am. Chem. Soc., 2008, 130, 10984-10995
https://doi.org/10.1021/ja801478n49
Synthetic And Mechanistic Aspects Of Cross-Coupling Of Nitroxyl Radicals Of 3-Imidazoline Series With Terminal Alkynes
Vasilevsky, S. F.; Krivenko, O. L.; Gorelik, V. R.; Alabugin, I. V.
Tetrahedron, 2008, 64, 8807-8814
https://doi.org/10.1016/j.tet.2008.06.08848
Organochalcogen Multication Species
Nenajdenko, V. G.; Shevchenko, N. E.; Balenkova, E. S.; Alabugin, I. V.
Handbook of Chalcogen Chemistry, 2007, 1, 417-453
https://doi.org/10.1039/9781849737456-0038247
Electronic Effects in Cycloaromatization Reactions: The Melting Pot of Theory and Experiment
Alabugin, I. V.; Breiner, B.; Manoharan, M.
Advances in Physical Organic Chemistry, 2007, 42, 1-35
https://doi.org/10.1016/S0065-3160(07)42001-946
DNA Damage-Site Recognition by Lysine Conjugates
Breiner, B.; Schlatterer, J. C.; Kovalenko, S. V.; Greenbaum, N. L.; Alabugin, I. V.
Proc. Natl. Acad. Sci., 2007, 104, 13016-13021
https://doi.org/10.1073/pnas.070570110445
Oxidative coupling of alkynes mediated by nitroxyl radicals under Sonogashira conditions and Pd-free catalytic approach to stable radicals of 3-imidazoline family with triple bonds
Vasilevsky, S. F.; Krivenko, O. L.; Alabugin, I. V.
Tetrahedron Lett., 2007, 48, 8246-8249
https://doi.org/10.1016/j.tetlet.2007.09.03144
Substituted Anilines: The Tug-Of-War between Pyramidalization and Resonance Inside and Outside of Crystal Cavities
Alabugin, I. V.; Manoharan, M.; Buck, M.; Clark, R. J.
THEOCHEM, 2007, 813, 21-27
https://doi.org/10.1016/j.theochem.2007.02.01643
Unmasking of aminoanthroquinone moiety through a ring-opening in the presence of copper salts and a subsequent cross-coupling/recyclization cascade
Vasilevsky, S. F.; Gornostaev, L. M.; Stepanov, A. A.; Arnold, E. V.; Alabugin, I. V.
Tetrahedron Lett., 2007, 48, 1867-1870
https://doi.org/10.1016/j.tetlet.2006.12.12942
Rehybridization as a General Mechanism for Maximizing Chemical and Supramolecular Bonding and a Driving Force for Chemical Reactions
Alabugin, I. V.; Manoharan, M.
J. Comp. Chem., 2007, 28, 373-390
https://doi.org/10.1002/jcc.2052441
Protected 32P-Labels in Deoxyribonucleotides: Investigation of Sequence Selectivity of DNA Photocleavage by Enediyne-, Fulvene-, and Acetylene-Lysine Conjugates
Breiner, B.; Schlatterer, J. C.; Kovalenko, S. V.; Greenbaum, N. L.; Alabugin, I. V.
Angew. Chem. Int. Ed., 2006, 45, 3666-3670
https://doi.org/10.1002/anie.20050447940
Ortho Effect in the Bergman Cyclization: Electronic and Steric Effects in Hydrogen Abstraction by 1-Substituted Naphthalene 5,8-Diradicals
Pickard IV, F. C.; Shepherd, R. L.; Gillis, A. E.; Dunn, M. E.; Feldgus, S.; Kirschner, K. N.; Shields, G. C.; Manoharan, M.; Alabugin, I. V.
J. Phys. Chem. A, 2006, 110, 2517-2526
https://doi.org/10.1021/jp056283539
Ortho Effect in the Bergman Cyclization: Comparison of Experimental Approaches and Dissection of Cycloaromatization Kinetics
Zeidan, T.; Kovalenko, S. V.; Manoharan, M.; Alabugin, I. V.
J. Org. Chem., 2006, 71, 962-975
https://doi.org/10.1021/jo052080138
Ortho Effect in the Bergman Cyclization: Interception of p-Benzyne Intermediate by Intramolecular Hydrogen Abstraction
Zeidan, T.; Manoharan, M.; Alabugin, I. V.
J. Org. Chem., 2006, 71, 954-961
https://doi.org/10.1021/jo051857n37
Two Photon Excitation of Substituted Enediynes
Kauffman, J. F.; Turner, J. M.; Alabugin, I. V.; Breiner, B.; Kovalenko, S. V.; Badaeva, E. A.; Masunov, A.; Tretiak, S.
J. Phys. Chem. A, 2006, 110, 241-251
https://doi.org/10.1021/jp056127y36
Thermodynamic and Strain Effects in the Competition Between 5-Exo-dig and 6-Endo-dig Cyclizations of Vinyl and Aryl Radicals
Alabugin, I. V.; Manoharan, M.
J. Am. Chem. Soc., 2005, 127, 12583-12594
https://doi.org/10.1021/ja052677y35
Triplet acetylenes as Synthetic Equivalents of 1,2-Dicarbenes. II. New Supramolecular Scaffolds from Photochemical Cycloaddition of Diarylacetylenes to 1,4-Cyclohexadienes
Zeidan, T.; Clark, R. J.; Kovalenko, S. V.; Ghiviriga, I.; Alabugin, I. V.
Chemistry Eur. Journal, 2005, 11, 4953-4962
34
5-Endo-dig Cyclizations – the "Poor Cousins" of the Radical Cyclization Family
Alabugin, I. V.; Manoharan, M.
J. Am. Chem. Soc., 2005, 127, 9534-9545
https://doi.org/10.1021/ja050976h33
Lysine-Enediyne Conjugates as Photochemically Triggered DNA Double-Strand Cleavage Agents
Kovalenko, S. V.; Alabugin, I. V.
Chem. Comm., 2005, 11, 1444-1446
https://doi.org/10.1039/B417012A32
Triplet acetylenes as Synthetic Equivalents of 1,2-Dicarbenes. Phantom n,p* State Controls Reactivity in Triplet Photocycloaddition
Zeidan, T.; Kovalenko, S. V.; Manoharan, M.; Clark, R. J.; Ghiviriga, I.; Alabugin, I. V.
J. Am. Chem. Soc., 2005, 127, 4270-4285
https://doi.org/10.1021/ja043803l31
Synthesis of Selectively Deuterated Fulvenes and Indenes from Enediynes
Peabody, S.; Breiner, B.; Kovalenko, S. V.; Patil, S.; Alabugin, I. V.
Org. Biomol. Chem., 2005, 3, 218-221
https://doi.org/10.1039/B417493N30
Effect of Double Hyperconjugation on the Apparent Donor Ability of s-Bonds: Insights From the Relative Stability of d-Substituted Cyclohexyl Cations
Alabugin, I. V.; Manoharan, M.
J. Org. Chem., 2004, 69, 9011-9024
https://doi.org/10.1021/jo048287w29
Blue-Shifted and Red-Shifted Hydrogen Bonds in Hypervalent Rare-Gas FRg-HY Sandwiches
Alabugin, I. V.; Manoharan, M.; Weinhold, F.
J. Phys. Chem. A., 2004, 108, 4720
https://doi.org/10.1021/jp049723l28
5-Exo-dig Radical Cyclization of Enediynes: The First Synthesis of Tin-Substituted Benzofulvenes
Kovalenko, S. V.; Peabody, S.; Manoharan, M.; Clark, R. J.; Alabugin, I. V.
Org. Lett., 2004, 6, 2457-2460
https://doi.org/10.1021/ol049122c27
Homoanomeric Effects in Saturated Heterocycles
Alabugin, I. V.; Manoharan, M.; Zeidan, T. A.
J. Am. Chem. Soc., 2003, 125, 14014-14031
https://doi.org/10.1021/ja037304g26
Control of Kinetics and Thermodynamics of [1,5]-Shifts by Aromaticity: A View Through the Prism of Marcus Theory
Alabugin, I. V.; Manoharan, M.; Breiner, B.; Lewis, F.
J. Am. Chem. Soc., 2003, 125, 9329-9342
https://doi.org/10.1021/ja035729x25
The Electronic Basis of Improper Hydrogen Bonding: A Subtle Balance of Hyperconjugation and Rehybridization
Alabugin, I. V.; Manoharan, M.; Peabody, S.; Weinhold, F.
J. Am. Chem. Soc., 2003, 125, 5973-5987
https://doi.org/10.1021/ja034656e24
Radical-Anionic C1-C5 and C1-C6 Cyclizations of Enediynes: Remarkable Substituent Effects in Cyclorearomatization Reactions
Alabugin, I. V.; Manoharan, M.
J. Am. Chem. Soc., 2003, 125, 4495-4509
23
1,2-Dications in Organic Main Group Systems
Nenajdenko, V. G.; Shevchenko, N. E.; Balenkova, E. S.; Alabugin, I. V.
Chem. Rev., 2003, 103, 229-282
https://doi.org/10.1021/cr000062822
Reactant Destabilization in the Bergman cyclization and Rational Design of Light and pH-Activated Enediynes
Alabugin, I. V.; Manoharan, M.
J. Phys. Chem. A, 2003, 107, 3363-3371
https://doi.org/10.1021/jp026754c21
C1-C5 Photochemical Cyclization of Enediynes
Alabugin, I. V.; Kovalenko, S. V.
J. Am. Chem. Soc., 2002, 124, 9052-9053
https://doi.org/10.1021/ja026630d20
Tuning Rate of the Bergman Cyclization of Benzannelated Enediynes with Ortho Substituents
Alabugin, I. V.; Manoharan, M.; Kovalenko, S. V.
Org. Letters, 2002, 4, 1119-1122
https://doi.org/10.1021/ol025505419
Stereoelectronic Effects and General Trends in Hyperconjugative Acceptor Ability of σ Bonds
Alabugin, I. V.; Zeidan, T. A.
J. Am. Chem. Soc., 2002, 124, 3175-3185
https://doi.org/10.1021/ja012633z18
Stereoelectronic interactions in cyclohexane, 1,3-dioxane, 1,3-oxathiane and 1,3-dithiane: W-effect, σC-X ↔ σ*C-H interactions, anomeric effect - what is really important?
Alabugin, I. V.
J. Org. Chem., 2000, 65, 3910-3919
https://doi.org/10.1021/jo991622+17
Energy Distribution and Redistribution and Chemical Reactivity. The Generalized Delta Overlap-Density Method for Ground State and Electron Transfer Reactions. A New Quantitative Counterpart of Electron Pushing
Zimmerman, H. E.; Alabugin, I. V.
J. Am. Chem. Soc., 2001, 123, 2265-2270
https://doi.org/10.1021/ja002402c16
Energy Distribution and Redistribution and Chemical Reactivity. Mechanistic and Exploratory Organic Photochemistry
Zimmerman, H. E.; Alabugin, I. V.
J. Am. Chem. Soc., 2000, 122, 952-953
https://doi.org/10.1021/ja993380115
Exploratory and Theoretical Host-Guest Photochemistry. Control of Reactivity with Host Variation and Theoretical Treatment with Stress Shaped Reaction Cavity
Zimmerman, H. E.; Alabugin, I. V.; Smolenskaya, V. N.
Tetrahedron, 2000, 56, 6821-6831
https://doi.org/10.1016/S0040-4020(00)00504-414
Dramatic Effects of Crystal Morphology on Solid State Reaction Course. Control by Crystal Disorder. Mechanistic and Exploratory Organic Photochemistry
Zimmerman, H. E.; Alabugin, I. V.; Chen, W.; Zhu, Z.
J. Am. Chem. Soc., 1999, 121, 11930-11931
https://doi.org/10.1021/ja992208u13
Phosphorus-Containing Allenes - Structure and Reactions with Electrophilic Reagents (Review)
Alabugin, I. V.; Brel, V. K.
Russ. Chem. Rev., 1997, 66, 225-245
12
Oxidative Properties of Triflic Anhydride - Oxidation of Alcohols and Sulfides
Nenajdenko, V. G.; Vertelezkij, P. V.; Koldobskij, A. B.; Alabugin, I. V.; Balenkova, E. S.
J. Org. Chem., 1997, 62, 2483-2486
https://doi.org/10.1021/jo962027011
Synthesis of Heterocyclic and Acyclic Derivatives of 1,2-Alkadienylphosphonic Acids Using Potassium Dichloroiodate(I)
Alabugin, I. V.; Sereda, G. A.; Abramkin, E. V.; Brel, V. K.; Zyk, N. V.; Zefirov, N. S.
J. Org. Chem (Russ.), 1996, 32, 1400-1403
9
SO3-Mediated Reaction of Phenylselenenylamide with 1,2-Alkadienylphosphonates
Alabugin, I. V.; Brel, V. K.; Zyk, N. V.; Zefirov, N. S.
Russian Chemical Bulletin, 1996, 45, 739-740
https://doi.org/10.1007/BF014358238
S-Tosylthiosufenylamides as Electrophilic Sulfosulfenylating Reagents
Zyk, N. V.; Beloglazkina, E. K.; Alabugin, I. V.; Kutateladze, A. G.; Zefirov, N. S.
Moscow State University Bulletin (Ser.2, Chemistry), 1996, 31, 68-71
7
Interaction of 3-Methyl-1,2-Butadienylphosphonic Acid Dichloride with SCl2
Alabugin, I. V.; Brel, V. K.
Journal of General Chemistry (Russia), 1995, 65, 1670-1672
6
Interaction of Potassium Dichloroiodate(I) with 1,2-Alkadienylphosphonic Acids Derivatives
Alabugin, I. V.; Sereda, G. A.; Abramkin, E. V.; Brel, V. K.; Zyk, N. V.; Zefirov, N. S.
Proceedings of Russian Academy of Science (Doklady Akademii Nauk), 1995, 345, 487-489
5
Molecular-Structure of Crystalline Product and Stereochemistry of Addition of 5,5-Dimethyl-2-Methoxy-2-Oxo-4-Chlorothio-1,2-Oxaphosphol-3-Ene to Cyclohexene
Chekhlov, A. N.; Alabugin, I. V.; Brel, V. K.; Zefirov, N. S.
Proceedings of Russian Academy of Science (Doklady Akademii Nauk), 1994, 335, 753-756
4
Electrophilic Sulfamatoselenenation of Olefins
Zyk, N. V.; Alabugin, I. V.; Kutateladze, A. G.; Kice, J. L.; Zefirov, N. S.
Proceedings of Russian Academy of Science (Doklady Akademii Nauk), 1994, 337, 208-210
3
Alkenylsulfenylchlorides - Synthesis and AdE Reactions of 2-Alkoxy-2-Oxo-3-R-4-Chlorothio-1,2-Oxaphosphol-3-Enes
Alabugin, I. V.; Brel, V. K.; Chekhlov, A. N.; Zefirov, N. S.; Stang, P. J.
Tetrahedron Letters, 1994, 35, 8275-8278
https://doi.org/10.1016/0040-4039(94)88301-72
Synthesis of 2-Alkoxy-5,5-Dimethyl-4-Chlorothio-1,2-Oxaphosphol-3-Enes
Alabugin, I. V.; Brel, V. K.; Zefirov, N. S.
Journal of General Chemistry (Russia), 1993, 63, 2387-2389
https://doi.org/10.1002/chin.1994432171